产品说明

应用

Catalyst for:

• [4C+2C] cycloadditions
• Cis-selective single-cleavagte skeletal cycloisomerization
• Diastereoselective Au-catalyzed intermolecular cyclopropanation
• Elucidating the mechanism of "endocyclic" skeletal rearrangement of 1,6-enynes
• Addition reactions

Gold Catalysts — 21st Century ′Gold Rush′

• Intermolecular addition of carbon nucleophiles to 1,5 and 1,6 enynes

包装

500 mg in glass bottle

基本信息

经验(实验)分子式	C42H63AuClO3P
分子量	879.34
MDL编号	MFCD11045473
PubChem化学物质编号	329762147
NACRES	NA.22

产品性质

形式	powder
质量水平	100
reaction suitability	core: gold reagent type: catalyst
mp	200-202 ℃
SMILES string	Cl[Au].CC(C)(C)c1ccc(OP(Oc2ccc(cc2C(C)(C)C)C(C)(C)C)Oc3ccc(cc3C(C)(C)C)C(C)(C)C)c(c1)C(C)(C)C
InChI	1S/C42H63O3P.Au.ClH/c1-37(2,3)28-19-22-34(31(25-28)40(10,11)12)43-46(44-35-23-20-29(38(4,5)6)26-32(35)41(13,14)15)45-36-24-21-30(39(7,8)9)27-33(36)42(16,17)18;;/h19-27H,1-18H3;;1H/q;+1;/p-1
InChI key	GCWCLHMEYZKZRO-UHFFFAOYSA-M

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves