产品介绍：
产品说明
应用
2-Benzyloxyphenylmagnesium bromide can be used:
- As a substrate in the iron-catalyzed coupling reaction of aryl Grignard reagents with unprotected bromophenols.
- As a substrate in the cross-coupling of Grignard reagents using diaryl titanates and ferric chloride.
- In one of the key synthetic steps for the total synthesis of an antibiotic caboxamycin.
包装
50 mL in Sure/Seal™
基本信息
| 经验(实验)分子式 | C13H11BrMgO |
| 分子量 | 287.43 |
| MDL编号 | MFCD08705262 |
| PubChem化学物质编号 | 24885138 |
产品性质
| 质量水平 | 100 |
| reaction suitability | reaction type: Grignard Reaction |
| 浓度 | 1.0 M in THF |
| 密度 | 1.047 g/mL at 25 ℃ |
| SMILES string | Br[Mg]c1ccccc1OCc2ccccc2 |
| InChI | 1S/C13H11O.BrH.Mg/c1-3-7-12(8-4-1)11-14-13-9-5-2-6-10-13;;/h1-9H,11H2;1H;/q;;+1/p-1 |
| InChI key | VELKJPFZDYXBDE-UHFFFAOYSA-M |
安全信息
| 象形图 |     |
| 警示用语： | Danger |
| 危险声明 | H225 - H302 - H314 - H335 - H351 |
| 预防措施声明 | P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235 |
| 危险分类 | Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 |
| 靶器官 | Respiratory system |
| 补充剂危害 | EUH014 - EUH019 |
| 储存分类代码 | 3 - Flammable liquids |
| WGK | WGK 3 |
| 闪点(F) | -4.0 - 5.0 °F - closed cup |
| 闪点(C) | -20 - -15 ℃ - closed cup |
| 个人防护装备 | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
