产品说明

应用

Reactant for synthesis of:

• Chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation
• Ligands for palladium-catalyzed stereoselective allylation reactions
• Ligands for enantioselective hydrogenations
• Josiphos analog as catalyst for asymmetric hydrogenation
• Ligands used in asymmetric hydrovinylation reactions

Reactant for enantioselective hydrogenation reactions catalyzed by Ru-(phosphine-oxazoline) complexes

包装

100, 500 mg in glass bottle

基本信息

经验(实验)分子式	C16H6ClF12P
分子量	492.63
MDL编号	MFCD01630852
PubChem化学物质编号	329761683
NACRES	NA.22

产品性质

reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand
质量水平	100
mp	25-29 ℃
官能团	phosphine
SMILES string	FC(F)(F)c1cc(cc(c1)C(F)(F)F)P(Cl)c2cc(cc(c2)C(F)(F)F)C(F)(F)F
InChI	1S/C16H6ClF12P/c17-30(11-3-7(13(18,19)20)1-8(4-11)14(21,22)23)12-5-9(15(24,25)26)2-10(6-12)16(27,28)29/h1-6H
InChI key	DFZQEHBNAJGDCT-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H261 - H314
预防措施声明	P231 + P232 - P280 - P305 + P351 + P338 - P310 - P422
危险分类	Skin Corr. 1B - Water-react. 3
储存分类代码	4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges