产品介绍：
产品说明
一般描述
1-Phenyl-1-trimethylsiloxyethylene is a styrene type silyl enol ether, reacts with formaldehyde and 2,4-pentanedione to yield the corresponding dihydropyran. It also undergoes Mukaiyama aldol reaction with aldehydes in water in the presence of amphiphilic calix[6]arene derivatives as surfactants.
应用
1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of:
- β-amino ketones in water via Mannich-type reaction
- cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction
包装
5, 25 g in glass bottle
基本信息
| 线性分子式 | C6H5C(=CH2)OSi(CH3)3 |
| 分子量 | 192.33 |
| Beilstein | 1306914 |
| EC 号 | 237-308-1 |
| MDL编号 | MFCD00008582 |
| PubChem化学物质编号 | 24854075 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 100 |
| 蒸汽密度 | >1 (vs air) |
| 测定 | 98% |
| 形式 | liquid |
| 折射率 | n |
| bp | 88-89 ℃/11 mmHg (lit.) |
| 密度 | 0.938 g/mL at 25 ℃ (lit.) |
| 储存温度 | 2-8℃ |
| SMILES string | C[Si](C)(C)OC(=C)c1ccccc1 |
| InChI | 1S/C11H16OSi/c1-10(12-13(2,3)4)11-8-6-5-7-9-11/h5-9H,1H2,2-4H3 |
| InChI key | AFFPCIMDERUIST-UHFFFAOYSA-N |
安全信息
| 象形图 |  |
| 警示用语： | Warning |
| 危险声明 | H315 - H319 - H335 |
| 预防措施声明 | P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 |
| 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| 靶器官 | Respiratory system |
| 储存分类代码 | 10 - Combustible liquids |
| WGK | WGK 3 |
| 闪点(F) | 168.8 °F - closed cup |
| 闪点(C) | 76 ℃ - closed cup |
| 个人防护装备 | Eyeshields, Gloves, type ABEK (EN14387) respirator filter |
