产品介绍：
产品说明
一般描述
6-Bromo-1,4-benzodioxane is an aryl halide. It can be synthesized from 1,4-benzodioxane, via bromination with bromine in acetic acid. It undergoes alkoxycarbonylation reaction with sodium tert-butoxide in the presence of CO to yield 2,3-dihydro-benzo[1,4]dioxine-6-carboxylic acid t-butyl ester.
应用
6-Bromo-1,4-benzodioxane may be used as a starting reagent in the synthesis of chiral diphosphines (SYNPHOS and DIFLUORPHOS).
包装
5 g in glass bottle
基本信息
| 经验(实验)分子式 | C8H7BrO2 |
| 分子量 | 215.04 |
| EC 号 | 257-817-2 |
| MDL编号 | MFCD00040750 |
| PubChem化学物质编号 | 24878339 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 100 |
| 测定 | 97% |
| 折射率 | n |
| bp | 259-260 ℃ (lit.) |
| 密度 | 1.598 g/mL at 25 ℃ (lit.) |
| SMILES string | Brc1ccc2OCCOc2c1 |
| InChI | 1S/C8H7BrO2/c9-6-1-2-7-8(5-6)11-4-3-10-7/h1-2,5H,3-4H2 |
| InChI key | LFCURAJBHDNUNG-UHFFFAOYSA-N |
安全信息
| 储存分类代码 | 10 - Combustible liquids |
| WGK | WGK 3 |
| 闪点(F) | 230.0 °F - closed cup |
| 闪点(C) | 110 ℃ - closed cup |
| 个人防护装备 | Eyeshields, Gloves, multi-purpose combination respirator cartridge (US) |
